羅英武課題組

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高翔 副教授,博士,博導

化學工程聯合國家重點實驗室(浙江大學)
           浙江大學化工系聚合與聚合物工程研究所
           地址:杭州市浙大路38號第十教學大樓4015B房間 (郵編:310027)
           電話:0571-87951280
           傳真:0571-87951612
           電子郵件:
gaox@

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簡歷

200911-今,浙江大學化學與生物工程學院
2005
-2009年,McMaster University,加拿大,博士
2002
-2005年,天津大學,碩士

1998
-2002年,天津大學,學士

 

研究興趣

鋰離子電池研究

聚合物新材料研發

聚合物膜加工

多形狀記憶材料
活性自由基聚合研究

 

 

3D打印多形狀記憶智能材料

 多形狀記憶智能材料的設計及制備

 

 

基于新型電極粘結劑動力鋰電池


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聚烯烴鋰電池隔膜擠出拉伸加工

主要在研項目


本征可彈性拉伸鋰離子全電池制備及其結構與性能實時分析(國家自然科學基金項目)

導電、導離子、高粘彈性理想電極粘結劑的制備與性能研究(國家自然科學基金項目)

聚合物分子鏈梯度結構設計實現多形狀記憶功能的研究(國家自然科學基金項目)

活性自由基高內相(細)乳液聚合過程研究(國家自然科學基金項目)

解決高比容量鋰離子電池壽命過短問題的關鍵技術研究(浙江省科學技術廳課題)

活性自由基乳液模板聚合法制備高性能聚合物多孔隔膜(教育部博士點基金)

聚合物鋰離子電池凝膠電解質的研究(浙江省科學技術廳課題)

輻照交聯動力鋰電池隔離膜材料的研究(浙江省科學技術廳課題)

 

 授權專利:

  

Block copolymer comprising a block with glass transition temperature higher than 100°C and method for preparing the same,美國專利 US 9,920,156 B2,許少宏,高翔,羅英武,授權日期:2018320

一種硫正極用水基粘結劑及制備方法201610832622.X高翔,李麗紅,羅英武,朱世平,授權日期:2018年4月27日,

一種水基電極粘結劑及制備方法,201610671015.X,高翔,鄭哲楠,羅英武,張帆,授權日期:2018年2月2日

嵌段共聚物增韌劑及制備方法與應用,ZL201510297485.X,朱月,高翔,羅英武,授權日期:2018112

基于嵌段共聚物的丙烯腈-苯乙烯-丙烯酸酯韌性樹脂的制備方法,ZL201510393636.1,黃杰,高翔,羅英武,授權日期:20171031

Poly((meth)acrylic acid-b-styrene-b-butadiene-b-styrene) block copolymer  latex and method for preparing the same, 美國專利,專利號 US 9,328,234 B2,羅英武,魏任重,高翔,授權日期:2016年5月3日

((甲基)丙烯酸-b-苯乙烯-b-(異戊二烯-co-丁二烯)-b-苯乙烯)嵌段共聚物膠乳及制備方法,ZL201410269519.X,高翔,羅英武,授權日期:2016824

Method for preparing porous anti-reflective thin film composed of hollow polymer nanoparticles, 美國專利,專利號 US 9,180,486 B2, 孫志娟,高翔,羅英武,授權日期:20151110

一種輻照交聯鋰離子電池隔膜及其制備方法, ZL201310196439.1高翔、盛偉、 李伯耿、羅英武、林葉剛、王永常,授權日期:2015429

含玻璃化溫度高于100oC嵌段的嵌段共聚物及制備方法,ZL201210243061.1,許少宏,高翔,羅英武,授權日期:2014716

高內相乳液可逆加成斷裂鏈轉移聚合制備多孔材料的方法,王安妮,高翔,羅英武,ZL201110370935.5授權日期:201464

一種V型梯度共聚物及其制備方法, ZL201210387662.X,郭云龍,高翔,羅英武,授權日期:2014416

聚苯乙烯-b-聚丁二烯嵌段共聚物納米膠乳及其制備方法,ZL201210084866.6,魏任重,高翔,羅英武,授權日期:2014129

由聚合物納米中空膠囊制備超級絕熱聚合物材料的方法,ZL201110289648.1,羅英武,高翔,葉長懷,授權日期:201387

聚((甲基)丙烯酸-b-苯乙烯-b-丁二烯-b-苯乙烯)嵌段共聚物膠乳及其制備方法,ZL201210067021.6,羅英武,魏任重,高翔,授權日期:2013925

聚((甲基)丙烯酸-b-丁二烯)嵌段共聚物及其制備方法,ZL201110119838.9,魏任重,高翔,羅英武,授權日期:20121114


 

代表性論文

1. Zhou, A.; Sim, R.; Luo, Y. W.; Gao, X., High-performance stretchable electrodes prepared from elastomeric current collectors and binders. J. Mater. Chem. A 2017, 5, 21550-21559.

2. Liu, D.; Wang, J.; Zhang, Y. B.; Liu, J.; Li, H. M.; Zhou, L.; Wu, S.; Gao, X., Preparation of core-shell structured Au@SiO2 nanocomposite catalyst with Au core size below 2 nm without high-temperature calcination procedure. J. Mater. Sci. 2018, 53, 8086-8097.

3. Wang, S.; Li, J. X.; Qi, M. F.; Gao, X.; Wang, W. J., Toward Maximizing the Mechanical Property of Interconnected Macroporous Polystyrenes Made from High Internal Phase Emulsions. Langmuir 2017, 33, 14295-14303.

4. Li, L.; Wang, Y.; Gao, X.; Zhu, S., Preparation and Evaluation of a New Water-Based Binder for Sulfur Cathode in Lithium-Sulfur Batteries. Journal of Chemical Engineering of Chinese Universities 2017, 31, 669-678.

5. Li, H.; Luo, Y.; Gao, X., Core-shell nano-latex blending method to prepare multi-shape memory polymers. Soft Matter 2017, 13, 5324-5331.

6. Zhu, Y.; Gao, X.; Luo, Y., Core-shell particles of poly(methyl methacrylate)-block-poly(n-butyl acrylate) synthesized via reversible addition-fragmentation chain-transfer emulsion polymerization and the polymer's application in toughening polycarbonate. Journal of Applied Polymer Science 2016, 133.

7. Zheng, Z.; Gao, X.; Luo, Y.; Zhu, S., Employing Gradient Copolymer To Achieve Gel Polymer Electrolytes with High Ionic Conductivity. Macromolecules 2016, 49, 2179-2188.

8. Yan, K.; Gao, X.; Luo, Y., Kinetics of RAFT Emulsion Polymerization of Styrene Mediated by Oligo(Acrylic Acid-b-Styrene) Trithiocarbonate. Aiche Journal 2016, 62, 2126-2134.

9. Li, H.; Gao, X.; Luo, Y., Multi-shape memory polymers achieved by the spatio-assembly of 3D printable thermoplastic building blocks. Soft Matter 2016, 12, 3226-3233.

10. Zhu, Y.; Bi, S.; Gao, X.; Luo, Y., Comparison of RAFT Ab Initio Emulsion Polymerization of Methyl Methacrylate and Styrene Mediated by Oligo(methacrylic acid-b-methyl methacrylate) Trithiocarbonate Surfactant. Macromolecular Reaction Engineering 2015, 9, 503-511.

11. Yan, K.; Gao, X.; Luo, Y., Well-Defined High Molecular Weight Polystyrene with High Rates and High Livingness Synthesized via Two-Stage RAFT Emulsion Polymerization. Macromolecular Rapid Communications 2015, 36, 1277-1282.

12. Yan, K.; Gao, X.; Luo, Y., Correlation between polydispersities of molecular weight distribution and particle size distribution in RAFT Emulsion Polymerization of Styrene. Journal of Polymer Science Part a-Polymer Chemistry 2015, 53, 1848-1853.

13. Luo, Y.; Wang, A.-N.; Gao, X., One-pot interfacial polymerization to prepare PolyHIPEs with functional surface. Colloid and Polymer Science 2015, 293, 1767-1779.

14. Guo, Y.; Gao, X.; Luo, Y., Suppressing the Long-Chain Branching in the Synthesis of Poly(styrene-b-butyl acrylate-b-styrene) in RAFT Emulsion Polymerization by Tuning the Interfacial Properties. Journal of Polymer Science Part a-Polymer Chemistry 2015, 53, 1464-1473.

15. Guo, Y.; Gao, X.; Luo, Y., Mechanical Properties of Gradient Copolymers of Styrene and n-Butyl Acrylate. Journal of Polymer Science Part B-Polymer Physics 2015, 53, 860-868.

16. Gao, X.; Sheng, W.; Wang, Y.; Lin, Y.; Luo, Y.; Li, B.-G., Polyethylene battery separator with auto-shutdown ability, thermal stability of 220 degrees C, and hydrophilic surface via solid-state ultraviolet irradiation. Journal of Applied Polymer Science 2015, 132.

17. Huang, J.; Zhao, S.; Gao, X.; Luo, Y.; Li, B., Ab Initio RAFT Emulsion Copolymerization of Styrene and Acrylonitrile. Industrial & Engineering Chemistry Research 2014, 53, 7688-7695.

18. Huang, J.; Zhao, S.; Gao, X.; Luo, Y.; Li, B., RAFT Ab Initio Emulsion Polymerization of Styrene Using Poly(acrylic acid)-b-polystyrene Trithiocarbonate of Various Structures as Mediator and Surfactant. Macromolecular Reaction Engineering 2014, 8, 696-705.

19. Guo, Y.; Zhang, J.; Xie, P.; Gao, X.; Luo, Y., Tailor-made compositional gradient copolymer by a many-shot RAFT emulsion polymerization method. Polymer Chemistry 2014, 5, 3363-3371.

20. Luo, Y.; Guo, Y.; Gao, X.; Li, B.-G.; Xie, T., A General Approach Towards Thermoplastic Multishape-Memory Polymers via Sequence Structure Design. Advanced Materials 2013, 25, 743-748.

21. Zhou, D.; Gao, X.; Wang, W.-j.; Zhu, S., Termination of Surface Radicals and Kinetic Modeling of ATRP Grafting from Flat Surfaces by Addition of Deactivator. Macromolecules 2012, 45, 1198-1207.

22. Ye, X.; Luo, Y.; Gao, X.; Zhu, S., Design and evaluation of a thermochromic roof system for energy saving based on poly(N-isopropylacrylamide) aqueous solution. Energy and Buildings 2012, 48, 175-179.

23. Luo, Y.; Wang, A.-N.; Gao, X., Pushing the mechanical strength of PolyHIPEs up to the theoretical limit through living radical polymerization. Soft Matter 2012, 8, 1824-1830.

24. Luo, Y.; Wang, A.-N.; Gao, X., Miniemulsion template polymerization to prepare a sub-micrometer porous polymeric monolith with an inter-connected structure and very high mechanical strength. Soft Matter 2012, 8, 7547-7551.

25. Gao, X.; Zhu, S., Modeling Analysis of Chain Transfer in Reversible Addition-Fragmentation Chain Transfer Polymerization. Journal of Applied Polymer Science 2011, 122, 497-508.

26. Feng, W.; Gao, X.; McClung, G.; Zhu, S.; Ishihara, K.; Brash, J. L., Methacrylate polymer layers bearing poly(ethylene oxide) and phosphorylcholine side chains as non-fouling surfaces: In vitro interactions with plasma proteins and platelets. Acta Biomaterialia 2011, 7, 3692-3699.

27. Gao, X.; Zhu, S.; Sheardown, H.; Brash, J. L., Nanoscale patterning through self-assembly of hydrophilic block copolymers with one chain end constrained to surface. Polymer 2010, 51, 1771-1778.

28. Gao, X.; Feng, W.; Zhu, S.; Sheardown, H.; Brash, J. L., Kinetic Modeling of Surface-Initiated Atom Transfer Radical Polymerization. Macromolecular Reaction Engineering 2010, 4, 235-250.

29. Gao, X.; Kucerka, N.; Nieh, M.-P.; Katsaras, J.; Zhu, S.; Brash, J. L.; Sheardown, H., Chain Conformation of a New Class of PEG-Based Thermoresponsive Polymer Brushes Grafted on Silicon as Determined by Neutron Reflectometry. Langmuir 2009, 25, 10271-10278.

30. Gao, X.; Feng, W.; Zhu, S.; Sheardown, H.; Brash, J. L., A facile method of forming nanoscale patterns on poly(ethylene glycol)-based surfaces by self-assembly of randomly grafted block copolymer brushes. Langmuir 2008, 24, 8303-8308.

31. Gao, X.; Liu, L.; Liu, X.; Zhang, B.; Lin, T., Permeation of Compressed and Supercritical Fluids through Porous Membranes. Journal of Chemical Engineering of Chinese Universities 2005, 19, 577-582.